rystal structure of ferrocenium-μ-chloro-bis[dichlorodimethyl-stannate(IV)],C14H22Cl5FeSn2
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چکیده
منابع مشابه
catena-Poly[[bis(5-chloro-2-nitrobenzoato)copper(II)]-bis(μ-5-chloro-2-nitrobenzoato)]
In the title compound, [Cu(2)(C(7)H(3)ClNO(4))(4)](n), the coordination geometry around each Cu(II) ion is distorted square-pyramidal. The CuO(5) coordination is formed by five O atoms from the carboxyl-ate groups of five 5-chloro-2-nitro-benzoate ligands. This coordination leads to the formation of centrosymmetric binuclear units which are edge-shared, forming a linear chain along the a axis, ...
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The crystal structure of the title complex, [Cu(2)(C(15)H(10)Cl(2)N(2)O(2))(2)(C(5)H(5)N)(2)], features centrosymmetric dimers. The Cu(II) ion is penta-coordinated in a quadratic pyramidal mode. The quadratic plane is formed by the O,O',N-tridentate ligand and a pyridine mol-ecule. The fifth coordination site is occupied by the O atom of another ligand showing a significantly longer Cu-O bond.
متن کاملApplications of Ferrocenium Salts in Organic Synthesis
Abstract Ferrocenium salts can be easily obtained from ferrocene by either synthetic preparation or in situ reaction. The ferrocenium ion can act as a one-electron oxidant and thus initiate or promote a range of radical processes. Ferrocene itself can donate electrons to suitable substrates, resulting in useful transformations. Ferrocenium salts can also act as mild Lewis acids. This paper high...
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In the crystal structure of the title compound, C6H5ClIN, the amino group engages in N-H⋯N hydrogen bonding, creating [100] chains. A Cl⋯I contact is observed [3.7850 (16) Å]. The parallel planes of neigbouring mol-ecules reveal highly offset π-stacking characterized by a centroid-centroid distance of 4.154 (1), a centroid-to-plane distance of 3.553 (3) and ring-offset slippage of 2.151 (6) Å.
متن کاملCrystal Structure of Schiff base Compound 2-[(2-chloro-4-nitrophenyl) iminomethyl] phenol
Single crystals of Schiff base compound 2-[(2-chloro-4-nitrophenyl) iminomethyl] phenol (1) were grown by the slow evaporation technique at room temperature. The crystal structure of the title compound was determined by single crystal X-ray diffraction. The title compound crystallizes in the monoclinic system, space group P21, with two symmetry independent molecules. Intramolecular O-H···N hydr...
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ژورنال
عنوان ژورنال: Zeitschrift für Kristallographie - New Crystal Structures
سال: 1998
ISSN: 2197-4578,1433-7266
DOI: 10.1524/ncrs.1998.213.14.543